Pt-KL zeolite catalysts of different preparation: Part I. Catalyst characterization |
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Affiliation: | 1. Department of Chemistry, University College London, 20 Gordon St, London, WC1H 0AJ, UK;2. Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX 76203-5017, USA |
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Abstract: | 0.8% Pt on KL zeolite was prepared by reduction with H2 and NaBH4. Transmission electron microscopy and X-ray diffraction were used for characterization of morphology of the metal particles; acidity of the zeolite framework was measured with IR spectra of adsorbed pyridine. Reduction by NaBHP4 produced rather large, needle-like Pt crystallites on the outer surface of zeolite grains which contained very little acidity. Subsequent hydrogen treatment brought about their severe sintering; at the same time, small crystallites appeared. A bimodal distribution was seen when the catalyst was reduced with hydrogen; this sample exhibited appreciable acidity. X-ray diffraction data showed the presence of Pt particles above noise level in the case of borohydride-reduced catalyst only, in agreement with EM data. |
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