A reinvestigation of the vibrational spectra of cyclooctatetraene and cyclooctatetraene-d8 |
| |
| Institution: | 1. Institut de Chimie de Nice, Université Côte d''Azur, CNRS, UMR 7272, 06108 Nice, France;2. L''Orme des Merisiers, Synchrotron SOLEIL, BP 48 Saint Aubin, 91192 Gif-sur-Yvette, France;3. ISA, Department of Physics and Astronomy, Aarhus University, 8000 Aarhus C, Denmark;4. Graduate School of Pharmaceutical Sciences, Kyushu University, Fukuoka, Japan;5. Department of Biogeochemistry, Japan Agency for Marine-Earth Science and Technology (JAMSTEC), 2-15 Natsushima, Yokosuka, Kanagawa 237-0061, Japan |
| |
| Abstract: | Band shapes in the gas phase infrared spectrum of cyclooctatetraene (COT) have been recorded in the 3500–250 cm?1 range. With these and the existing vibrational data for COT and COT-d8, revised assignments of the fundamental modes have been made for both compounds. A normal coordinate analysis based on D2d symmetry has been carried out and used to support the vibrational assignments. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
