The role of iron(II) phthalocyanine as a catalyst in Wacker oxidation of 1-decene |
| |
| Institution: | 1. State Key Laboratory of Functions and Applications of Medicinal Plants & School of Pharmaceutical Sciences, Guizhou Medical University, 550004 Guiyang, China;2. Key Lab of Green Chemistry and Technology, Ministry of Education College of Chemistry, Sichuan University, 610064 Chengdu, China;1. Chemistry of Interaction Plasma Surface (ChIPS), University of Mons, Belgium;2. Elettra - Sincrotrone Trieste S.C.p.A., Trieste, Italy;3. Research Group on Carbon Nanostructures (CARBONNAGe), University of Namur, Belgium;1. Department of Chemistry, Kahramanmaraş Sütçü Imam University, Kahramanmaraş, 46050–9, Turkey;2. Department of Chemistry, Faculty of Science, Atatürk University, 25240, Erzurum, Turkey;1. School of Advanced Medical Technologies, Tehran University of Medical Sciences, Tehran, Iran;2. Hematology Department, Faculty of Medical Science, Tarbiat Modares University, Tehran, Iran;3. Chemical Engineering Department, Faculty of Engineering, Tarbiat Modares University, Tehran, Iran;4. Nano Drug Delivery Research Center, Kermanshah University of Medical Sciences, Kermanshah, Iran;5. Department of Toxicology & Pharmacology, Pharmaceutical Sciences Branch, Islamic Azad University (IAUPS), Tehran, Iran |
| |
| Abstract: | The Wacker oxidation of 1-decene to 2-decanone by dioxygen catalyzed by Pd(OAc)2, hydroquinone and iron(II) phthalocyanine (FePc) in acidic aqueous dimethylformamide gives high yield m 40 min at room temperature. The major factors controlling the activity of the multi-component catalyst are the structure and morphology of the FePc, which were analyzed by IR spectroscopy, X-ray powder diffraction, scanning electron microscopy and BET surface area measurement. The dimeric μ-oxo(1) form of FePc is highly active, has higher surface area, and is less crystalline than the inactive monomeric β-FePc. The rate of oxidation using the most active catalyst is limited by the solubility of 1-decene in aqueous DMF. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
