Vibrational spectra of dimethyl aluminium hydride |
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Institution: | 1. Institute of Chemistry, Martin Luther University Halle-Wittenberg, Kurt-Mothes-Straße 2, 06120 Halle, Germany;2. Interdisciplinary Center of Materials Science, Martin Luther University Halle-Wittenberg, Heinrich-Damerow-Straße 4, 06120 Halle, Germany;3. Institute of Physics, Martin Luther University Halle-Wittenberg, Von-Danckelmann-Platz 3, 06120 Halle, Germany |
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Abstract: | The infrared and Raman spectra of dimethyl aluminium hydride and its partially deuterated isotopomers are reported and assigned. On the basis of variable temperature studies, coupled with isotope shifts and normal coordinate analysis, it is shown that the vapour phase infrared spectrum at room temperature may be interpreted as predominantly that of the dimer, with smaller amounts of trimer. |
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