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The polarized infrared and Raman spectra of crystalline ammonium trifluoromethanesulphonate
Affiliation:1. Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia;2. Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk 660079, Russia;3. Laboratory of Optical Materials, Institute of Chemistry, FEB RAS, Vladivostok 690022, Russia
Abstract:The infrared and Raman spectra of NH4CF3SO3 were obtained and analysed and an assignment was proposed for the observed bands. The assignment of some anion bands was supported by means of the polarized spectra of monocrystals. The fundamental frequencies of the anion were used for a normal coordinate calculation.
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