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Silver-catalyzed cycloisomerization of 1,n-allenynamides
Authors:Garcia Pierre  Harrak Youssef  Diab Lisa  Cordier Pierre  Ollivier Cyril  Gandon Vincent  Malacria Max  Fensterbank Louis  Aubert Corinne
Affiliation:UPMC Universite? Paris 06, Sorbonne Universite?s, Institut Parisien de Chimie Mole?culaire (UMR CNRS 7201), Paris, France.
Abstract:A variety of allenynamides can undergo cycloisomerization reactions in the presence of silver triflate thus leading to the formation of N-containing heterocycles incorporating cross-conjugated trienes. Access to new dienic 4-piperidinone and azepane motifs was achieved. An extension to one-pot tandem sequences involving silver-catalyzed cycloisomerization/Diels-Alder reaction was also examined.
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