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Regioselective Reaction of N1-Benzyl-N2-(4-nitrophenyl)ethanediamide and Acetylenic Esters
Authors:Issa?Yavari  author-information"  >  author-information__contact u-icon-before"  >  mailto:yavarisa@modares.ac.ir"   title="  yavarisa@modares.ac.ir"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author,Loghman?Moradi,Farough?Nasiri,Hoorieh?Djahaniani
Affiliation:(1) Department of Chemistry, Tarbiat Modarres University, P.O. Box 14115-175, Tehran, Iran
Abstract:Summary. The regioselective reaction of N1-benzyl-N2-(4-nitrophenyl)ethanediamide with dialkyl acetylenedicarboxylates or alkyl propiolates in the presence of triphenylphosphine leads to dialkyl 4-benzylamino-1-(4-nitrophenyl)-5-oxo-2,5-dihydro-1H-pyrrole-2,3-dicarboxylates or alkyl 4-benzylamino-1-(4-nitrophenyl)-2-oxo-5-pyrrolidinecarboxylates in good yields.
Keywords:. Intramolecular Wittig reaction   Acetylenic esters   Triphenylphosphine   2-Oxo-5-pyrrolidines   5-Oxo-2,5-dihydro-1H-pyrroles.
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