Influence of Reagent Structure on the Rate and Mechanism of the Reaction of Aryloxiranes with Benzoic Acids |
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| Authors: | Shpan'ko I. V. Sadovaya I. V. |
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| Affiliation: | (1) Donets'k National University, 24 Universytets'ka Vul., 83055 Donets'k, Ukraine |
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| Abstract: | The kinetics of the reactions of aryloxiranes (XC6H4CH(O)CH2, X = H, 4-Cl, 3-NO2, 4-NO2, and 3-Br and 4-Br in part) with arylcarboxylic acids (YC6H4(3) COOH, Y = H, 3-Br, 3-NO2, 3,5-(NO2)2, and 4-OCH3 in part) in acetonitrile have been studied at 343 K. Non-additive effects of the structural factors have been estimated quantitatively by cross-correlation analysis. The mechanism of the reactions is discussed. |
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| Keywords: | aryloxiranes benzoic acids kinetics correlation analysis mechanism |
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