Gold-catalyzed intermolecular hetero-dehydro-diels-alder cycloaddition of captodative dienynes with nitriles: a new reaction and regioselective direct access to pyridines |
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| Authors: | Barluenga José Fernandez-Rodríguez Manuel Angel García-García Patricia Aguilar Enrique |
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| Affiliation: | Instituto Universitario de Química OrganometAlica "Enrique Moles", Unidad Asociada al CSIC, Universidad de Oviedo, 33006-Oviedo, Spain. barluenga@uniovi.es |
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| Abstract: | For the first time, nitriles are used as 2pi electron component in a gold-catalyzed intermolecular hetero-dehydro-Diels-Alder cycloaddition with captodative enynes leading to the regioselective formation of pyridines. |
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