Construction of model hamiltonians in framework of Rayleigh-Schrödinger perturbation theory |
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Authors: | V Kvasnička |
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Institution: | 1. The J. Heyrovsky Institute of Physical Chemistry and Electrochemistry, Czechosl. Acad. Sci., Prague
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Abstract: | A theory of the model Hamiltonians within the framework of Rayleigh-Schrödinger perturbation theory is elaborated. The approach of a model Hamiltonian is based on the assumption that if it is diagonalized in a chosen model space it will yield eigenvalues of the original Hamiltonian in the entire Hilbert space. The theory of the model Hamiltonians may be fruitful as a theoretical background for the study of effective Hamiltonians and as natural extension of the standard Rayleigh-Schrödinger perturbation theory. |
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