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The thermodynamics of mixing C6 and C7 compounds with a bicyclic compound at infinite dilution |
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| Authors: | T M Letcher R Baxter |
| Institution: | (1) Department of Chemistry, Rhodes University, 6140 Grahamstown, South Africa |
| Abstract: | The activity coefficients at infinite dilution have been measured at 25°C for cyclohexane, cyclohexene, 1,3-cyclohexadiene, 1,4-cyclohexadiene, benzene, n-hexane, 1-hexene, 1-hexyne, n-heptane, 1-heptene and 1-heptyne in decahydronaphthalene, bicyclohexyl, 1,2,3,4-tetrahydronaphthalene and cyclohexylbenzene. These results, together with previously determined H m E and V m E have been used to calculate the partial molar excess thermodynamic properties of mixing at infinite dilution. |
| Keywords: | Activity coefficients at infinite dilution gas-liquid chromatography decalin bicyclohexyl tetralin cyclohexylbenzene C6 and C7 compounds thermodynamics of mixing partial molar volumes enthalpies entropies and Gibbs function |
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