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纳米级锂离子电池正极材料LiFePO4
引用本文:梁风,戴永年,易惠华,熊学.纳米级锂离子电池正极材料LiFePO4[J].化学进展,2008,20(10):1606-1611.
作者姓名:梁风  戴永年  易惠华  熊学
作者单位:( 昆明理工大学材料与冶金工程学院 真空冶金国家工程实验室 昆明 650093)
摘    要:LiFePO4以其价格便宜,稳定性好,无毒等优点而倍受关注。但是非纳米LiFePO4的电子导电率低及扩散系数小限制了其在锂离子电池领域的大规模应用。而纳米电极材料以其特有的优点很好的解决了这些问题。本文主要综述了国内外合成纳米级LiFePO4 的不同方法及所得材料的对电化学性能和相关机理,以及纳米LiFePO4作为锂离子正极材料存在的问题。

关 键 词:锂离子电池  磷酸铁锂  纳米材料
收稿时间:2007-11-29
修稿时间:2008-03-21

Nano-Scale LiFePO4 as Lithium Ion Battery Cathode Materials
Liang Feng |Dai Yongnian|Yi Huihua|Xiong Xue.Nano-Scale LiFePO4 as Lithium Ion Battery Cathode Materials[J].Progress in Chemistry,2008,20(10):1606-1611.
Authors:Liang Feng |Dai Yongnian|Yi Huihua|Xiong Xue
Institution:(National Engineering Laboratory of Vacuum Metallurgy, Faculty of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming, 650093, China )
Abstract:Lithium iron phosphate (LiFePO4 ) has been attracting enomous research interest for its lower cost, high stability, non-toxicity. The extensive use of LiFePO4 in Li-ion batteries is limited by poor electronic conductivity and low lithium ion diffusion limited the application of non-nanos-cale LiFePO4. Nano-scale electrode materials overcome these disadvantages. This paper overcomes chiefly the methods of synthesizing nano-scale LiFePO4, the electrochemical performance of nano-scale LiFePO4, the mechanism of nano-scale LiFePO4 some problems of nano-LiFePO4 as cathode in Li-ion batteries.
Keywords:lithium batteries  lithium iron phosphate  nano-scale materials
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