| Synthesis and Crystal Structure of N-（（6-chloropyridin-3-yl）methyl）-6-ethoxy-N-ethyl-3-nitropyridin-2-amine |
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| 作者姓名： | 吴道新 刘民华 柳爱平 黄明智 胡志彬 任叶果 刘兴平 唐明 左文清 |
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| 作者单位： | [1]School of Chemistry andBiological Engineering, ChangshaUniversity of Science and Technology, Changsha 410076, China [2]National Engineering Research CenterforAgrochemicals, HunanResearch Institute of Chemical Industry, Changsha 410007, China [3]College of Chemical Engineering, Xiangtan University, Xiangtan, Hunan 411105, China |
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| 基金项目： | Supported by the National Basic Research Program of China （973 Program,2010CB126104）; the NNSFC （Nos. 20572019 and 20872033）; National Twelfth-five Key Project of China （Nos. 2011BAE06B01 and 2011BAE06B02）; the NSF of Hunan Province （11JJ2006, 11JJ3022 and 10JJ3053）; Science Plan of Hunan Province （2010FJ2003）; research condition innovation of Hunan Province （2010PT2058） |
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| 摘 要： | The title compound N-((6-chloropyridin-3-yl)methyl)-6-ethoxy-N-ethyl-3-nitropyri-din-2-amine(4) was synthesized by reacting the mixture of 6-chloro-2-ethoxy-3-nitropyridine(1) and 2-chloro-6-ethoxy-3-nitropyridine(2) with 3,and its structure was determined by X-ray single-crystal diffraction.The crystal belongs to the monoclinic system,space group P21/n with a = 7.3441(2),b = 9.9041(3),c = 11.7368(3) ,α = 101.410(2),β = 102.1340(10),γ = 99.594(2)o,μ = 0.260 mm-1,Mr = 336.78,V = 798.58(4)3,Z = 2,Dc = 1.401g/cm3,F(000) = 352,T = 296(2) K,R = 0.0210 and wR = 0.1053.
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| 关 键 词： | synthesis crystal structure N-((6-chloropyridin-3-yl)methyl)-6-ethoxy-N-ethyl-3-nitropyridin-2-amine insecticidal and fungicidal activities |
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