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Palladium–quaternary phosphonium phase transfer catalyst brush assembly as reusable and environmentally benign catalyst for coupling of aryl halides and sodium tetraphenylborate in neat water
Authors:Abdol R Hajipour  Ghobad Azizi
Institution:1. Pharmaceutical Research Laboratory, Department of Chemistry, Isfahan University of Technology, Isfahan, IR, Iran;2. Department of Neuroscience, Medical School, University of Wisconsin, Madison, WI, USA
Abstract:A first example of simultaneous covalent anchoring of a palladate anion–phosphonium cation matrix on the surface of silica nanoparticles and application in the Suzuki coupling reaction of a variety of different haloarenes and sodium tetraphenylborate in neat aqueous media without the addition of any organic co‐solvent are described. Copyright © 2015 John Wiley & Sons, Ltd.
Keywords:silica nanoparticles  sodium tetraphenylborate  Suzuki coupling reaction  environmentally benign reaction
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