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Synthesis of 5‐substituted 1H‐tetrazoles using a recyclable heterogeneous nanonickel ferrite catalyst
Authors:Fatemeh Abrishami  Maryam Ebrahimikia  Fatemeh Rafiee
Affiliation:1. Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Malek‐ashtar University of Technology, Tehran, Iran;2. Department of Chemistry, Faculty of Physics‐Chemistry, Alzahra University, Tehran, Iran
Abstract:An efficient method was developed for the [2 + 3] cycloaddition of sodium azide with nitriles to afford 5‐substituted 1H‐tetrazoles using nanonickel ferrite (NiFe2O4) as an effective heterogeneous catalyst in dimethylformamide. The main advantages of this method are high yields, simple methodology and easy work‐up. The catalyst can be recovered and reused for several cycles with predictable activity. Copyright © 2015 John Wiley & Sons, Ltd.
Keywords:heterogeneous catalyst  nickel ferrite nanoparticles  cycloaddition  5‐substituted 1H‐tetrazoles
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