Syntheses,structures and properties of complexes of indole-3-propionic acid |
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Authors: | Xiu-jun Deng Qing Yu He-Dong Bian Hai-Dong Ju Bao-Ling Wang |
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Affiliation: | 1.Department of Chemical Science and Technology,Kunming University,Kunming,People’s Republic of China;2.Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Pharmacy,Guangxi Normal University,Guilin,People’s Republic of China |
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Abstract: | Three complexes [Zn2(IPA)2(phen)4](HIPA)2(NO3)2·H2O (1), {[Zn(IPA)2(bipy)]·3H2O}n (2), and {[Mn(IPA)2(bipy)(H2O)]·2H2O}n (3) (HIPA = indole-3-propionic acid, phen = 1,10-phenanthroline, bipy = 4,4′-bipyridine) were synthesized and characterized by physico-chemical and spectroscopic methods. Complex 1 displays a zero-dimensional structure, whilst 2 and 3 show one-dimensional chains, which are linked into supramolecular networks through hydrogen bonding interactions and/or π···π stacking interactions. The luminescence properties of complexes 1 and 2 were investigated. |
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