Contribution from two types of peroxyl radicals to cyclohexanol oxidation and their reactivity |
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| Authors: | E. G. Moskvitina S. V. Puchkov I. M. Borisov A. L. Perkel’ |
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| Affiliation: | 1.Faculty of Chemistry and Technology,Kuzbass State Technical University,Kemerovo,Russia;2.Faculty of Natural Sciences and Geography,Bashkir State Pedagogical University,Ufa,Bashkortostan, Russia |
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| Abstract: | The oxygen uptake kinetics in the liquid-phase oxidation of cyclohexanol initiated by cumyl peroxide in the presence of inhibitors (ionol and nitrobenzene) has been investigated (373 K, ortho-dichlorobenzene as the solvent). The relative contributions from the hydroperoxyl and α-hydroxycyclohexylperoxyl radicals to chain propagation has been determined. The rate constants for the reactions of these radicals with the alcohol have been determined. |
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