Synthesis,characterization and reactivity of some rhenium phosphite complexes |
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| Affiliation: | 1. 101, Sec. 2, Kuang Fu Road, Department of Biomedical Engineering and Environmental Sciences, National Tsing Hua University, Hsinchu 30013, Taiwan;2. Department of Civil and Environmental Engineering, University of Delaware, Newark 19716, DE, USA;3. 1001, University Road, Institute of Environmental Engineering, National Chiao Tung University, Hsinchu 30010, Taiwan |
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| Abstract: | The preparation and characterization of some Re(III), Re(IV) and Re(V) chloro phosphite complexes are reported. Both Re(III) and Re(IV) complexes react with sodium borohydride, yielding the corresponding polyhydrides, ReH5[P(OEt)3]3 and ReH7[P(OEt)3]2. The thermal and photochemical reactivity of these complexes is described. |
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