Studies on the structural,kinetic and thermodynamic parameters of cellulose acetate membranes |
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Affiliation: | 1. Department of Electronic Science, University of Calcutta, 92A.P.C. Road, Kolkata 700009, India;2. Department of Polymer Science and Technology, University of Calcutta, 92A.P.C. Road, Kolkata 700009, India;1. Department of Earth and Environmental Sciences, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada;2. Aquanty Inc., Waterloo, Ontario N2L 5C6, Canada;3. Department of Atmospheric Sciences, University of Utah, Salt Lake City, UT 84112-0102, USA |
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Abstract: | Hydraulic permeability (Lp), osmotic permeability (Lπ) and tritium permeability (ωTHO) have been measured for cellulose acetate membranes of varying water contents (Øw). The porosity factor (gp) has been calculated using the above parameters. Thermodynamic properties such as ΔG≠, ΔH≠, and ΔDwS≠ are estimated for the activated complex of the solute in the membrane phase using conductance measurements. |
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