An X-ray photoelectron spectroscopic study of some copper(II) tetraaza complexes |
| |
| Institution: | 1. Institute of Agro-Product Processing, Jiangsu Academy of Agricultural Sciences, Nanjing, 210014, PR China;2. Ministerial and Provincial Co-Innovation Center for Endemic Crops Production with High-quality and Effciency in Loess Plateau, Agriculture College of Shanxi Agricultural university, Taigu, Shanxi 030801, PR China;3. Key Laboratory of Green and Low-carbon Processing Technology for Plant-based Food of China National Light Industry Council, Beijing Technology and Business University, Beijing, 100048, PR China;4. Institute of Economic Crops, Shanxi Agricultural University, Taiyuan, Shanxi 030031, PR China;5. College of Food Science and Engineering, Shanxi Agricultural University, Taigu, Shanxi 030801, PR China |
| |
| Abstract: | A selected series of copper(II) tetraaza complexes, involving open-chain and macrocyclic ligands, has been studied by X-ray photoelectron spectroscopy. The binding energy data obtained are interpreted in terms of the structures of these complexes with particular reference to the existence of π-electron delocalisation over metal and ligand, peripheral ring substituents, cation-anion interaction and hydration water. It is apparent that the degree of cation-anion interaction and photoreduction is a function of the existing experimental conditions. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
