Light-assisted transport of nitric oxide across membranes containing nitrosyl chloride solutions |
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| Affiliation: | 1. School of Energy Science and Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China;2. Collaborative Innovation Center of Coalbed Methane (Shale Gas) in Central Plains Economic Zone, Jiaozuo, Henan 454000, China;1. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi''an 710072, China;2. Research & Development Institute of Northwestern Polytechnical University in Shenzhen, Shenzhen 518057, China;3. Department of Material Science and Engineering, Shanghai University, Shanghai 200072, China |
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| Abstract: | Experimental evidence for the light-assisted concentration of nitric oxide taking part in a reversible photochemical reaction in a solution is presented. For the system, nitrosyl chloride-nitric oxide, a gradient of light energy across the membrane sandwich containing nitrosyl chloride solution results in a gradient of nitric oxide concentration across the membrane. For the experimental conditions employed, nitric oxide concentration ratios of up to 15 were obtained. The experimental results are explained using an “equilibrium-facilitation” model. The photodiffusion membrane configuration of the kind discussed can be used for the chemical storage of solar energy |
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