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Retention of regiochemistry of monosubstituted allyl acetates in the ruthenium catalysed allylic alkylation with malonate anion
Authors:Kawatsura Motoi  Ata Fumio  Hayase Shuichi  Itoh Toshiyuki
Institution:Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori, 680-8552, Japan. kawatsur@chem.tottori-u.ac.jp
Abstract:In the RuCl2(p-cymene)/PPh3 catalysed regioselective allylic alkylation of monosubstituted allyl acetates with malonate anion, the selective substitution at the position originally substituted with acetate was observed.
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