Synthesis of optically active forms of sulcatol : The aggregation pheromone in the scolytid beetle, Gnathotrichus sulcatus |
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| Authors: | K Mori |
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| Institution: | Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo 113, Japan |
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| Abstract: | (S)-(+)-Sulcatol (1) and its antipode (1′) were synthesized from (R)-(−)-glutamic acid (2), and its antipode (2′), respectively. This established the absolute configurations of both enantiomers of sulcatol and afforded key materials to study the relationship between pheromone activity and chirality. |
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