Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities |
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| Authors: | Liu Yunling Kravtsov Victor Ch Larsen Randy Eddaoudi Mohamed |
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| Affiliation: | Department of Chemistry, University of South Florida, 4202 E. Fowler Ave. (SCA400), Tampa, FL 33620, USA. eddaoudi@cas.usf.edu |
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| Abstract: | Two novel porous anionic zeolite-like metal-organic frameworks, rho-ZMOF and sod-ZMOF, have been synthesized by metal-ligand-directed assembly of rigid and directional tetrahedral building units, InN4 synthesized in situ, and doubly deprotonated bis(bidentate) imidazoledicarboxylic acid ligands (HImDC) in the presence of different structure directing agents (SDAs). |
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