Synthesis and Characterization of (Z)-1-[2-(Triarylstannyl)vinyl]-1-Cyclohexanols and their Arylhalostannyl Derivatives |
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| Authors: | Fu Fang Xin Shan Xi Lin Fu Yu Jie Huade Pan Bernard Mahieu Marcel Gielen Franois Kayser Rudolph Willem |
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| Institution: | Fu Fang Xin,Shan Xi Lin,Fu Yu Jie,Huade Pan,Bernard Mahieu,Marcel Gielen,François Kayser,Rudolph Willem |
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| Abstract: | 1-Ethynyl-1-cyclohexanol reacts with a triaryltin hydride Ar3SnH (Ar = phenyl, p-tolyl) and generates the corresponding (Z)-1-2-(triarylstannyl)vinyl]-1-cyclohexanol. The product obtained reacts with one or two equivalents of halogen (ICl or I2) to form the associated (Z)-1-2-(diarylhalostannyl)-vinyl]-1-cyclohexanol or (Z)-1-2-(aryldihalostannyl)vinyl]-1-cyclohexanol, respectively. All compounds were characterized by elemental analysis, 1H, 13C, 119Sn NMR and Mössbauer spectroscopy. |
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| Keywords: | Arylhalostannyl compounds syntheses characterization |
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