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Concurrent crystallization in polypropylene/nylon-6 blends using maleic anhydride grafted polypropylene as a compatibilizing agent
Authors:Hyuk-Soo Moon  Byung-Kyu Ryoo  Jung-Ki Park
Abstract:This paper describes the nonisothermal crystallization of molten blends of two semicrystalline polymers, polypropylene (PP) and Nylon-6 (N6). A discussion details the effect of the concentration of the compatibilizing agent, maleic anhydride grafted polypropylene (MAH-g-PP), on the crystallization behavior. The crystallization thermograms showed one crystallization peak or two crystallization peaks, which were significantly affected by the presence of MAH-g-PP. The crystallization temperature of N6 levels off down as the concentration of MAH-g-PP increases, whereas that of PP stays at a roughly constant temperature. These blends containing the compatibilizing agent exhibited concurrent crystallization at the crystallization temperature of PP. The crystallization behavior are also studied by optical microscopy under crossed polarizers. © 1994 John Wiley & Sons, Inc.
Keywords:polypropylene  Nylon-6  maleic anhydride grafted polypropylene  concurrent crystallization  DSC  sub-Tm exotherm
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