α-Funktionelle 2-Methylphenylphosphane, 2-(HE?CH2)?C6H4?PH2 (E: O,NR, PH) I. Darstellung,Metallierungs- und Silylierungsverhalten |
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Authors: | Jutta Kalbitz Elke Leißring Harry Schmidt |
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Abstract: | α-Functionalized 2-Methylphenyl Phosphines, 2-(HE? CH2)? C6H4? PH2 (E: O, NR, PH) I. Preparation, Deprotonation and Silylation Behaviour By reaction of different ortho-substituted phenyl phosphonates 2-X? C6H4? PO3R2 (X = COOR, CONHR, PO3R2) with LiAlH4 α-functionalized 2-methylphenyl phosphines 2-(HE? CH2)? C6H4? PH2 (E: O, NPh, PH) are accessible. The title compounds are characterized by deprotonation and silylation experiments. |
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Keywords: | α -Functionalized methylphenyl phosphines |
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