Beiträge zur Chemie der Alkylverbindungen von Übergangsmetallen. 61. Darstellung und Kristallstruktur von Tetramethyltitan-1,2-bis(dimethylphosphino)ethan |
| |
| Authors: | K-H Thiele H Windisch H Schumann G Kociok-Khn |
| |
| Institution: | K.-H. Thiele,H. Windisch,H. Schumann,G. Kociok-Köhn |
| |
| Abstract: | Contributions to the Chemistry of Transition Metal Alkyl Compounds. 61. Preparation and Crystal Structure of Tetramethyltitanium-1,2-bis(dimethylphosphino)ethane The title complex 1 was synthesized by addition of 1,2-bis(dimethylphosphino)ethane to a solution of tetramethyltitanium in diethylether. The complex was characterized by 1H, 13C and 31P NMR spectra and by X-ray crystal structure analysis. 1 consists of two independent molecules with distorted octahedral structure. |
| |
| Keywords: | Tetramethyltitanium-1 2-bis(dimethylphosphino)-ethane NMR data crystal structure |
|
|
