Dielectric relaxations in poly(thiocarbonates) |
| |
Authors: | R Díaz Calleja L Gargallo D Radi |
| |
Institution: | R. Díaz Calleja,L. Gargallo,D. Radić |
| |
Abstract: | The dielectric absorptions observed on six poly(thiocarbonates) (PTC) containing different substituents in the interphenylic carbon atom are subjected to a study. The α relaxation process associated with the glass transition temperature, which appears at the highest temperature studied, is overlapped with a strong conductive component. Between 80 and 100°C dielectric activity (β) is observed, which is related to structural relaxation phenomena. Polymers with double substitution on the interphenylic carbon atom show a γ relaxation with an activation energy of ca. 11 kcal mol?1 while those where the carbon atom is linked to a cyclohexyl group show higher activation energies and their respective characteristics. A cryogenic absorption around ?120°C, for at least three polymers with an activation energy of about 5 kcal mol?1, is detected. © 1994 John Wiley & Sons, Inc. |
| |
Keywords: | poly(thiocarbonates) dielectric relaxation conductivity physical aging molecular motions |
|
|