Franck-Condon factors and r -centroids for the E 1Πu- X 1Σ g+ system of Ag2 |
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| Authors: | M Kuzmanovi&#; M A Khakoo V Bojovi&#; and A Anti&#;-Jovanovi&#; |
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| Institution: | (1) Faculty of Physical Chemistry, University of Belgrade, P.O.Box 137, 1001 Belgrade, Serbia;(2) Physical Department, California State University Fullerton, Fullerton, CA 92834, USA |
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| Abstract: | An array of Franck-Condon factors and r-centroids is reported for the bands of the E
1Πu-X
1Σ
g
+
system of the Ag2 molecule. Both parameters were calculated using the Morse and Rydberg-Klein-Rees potentials. The results showed a reasonable
agreement between the two sets of data for transitions, including lower vibrational levels (v ≤ 6). Differences appear with increasing v, but two sets of calculated Franck-Condon factors follow the same pattern. The predicted intensity distribution was compared
with the estimated band intensity in the experimental spectrum.
The text was submitted by the authors in English. |
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| Keywords: | |
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