High-voltage asymmetric supercapacitors operating in aqueous electrolyte |
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Authors: | V Khomenko E Raymundo-Piñero E Frackowiak F Béguin |
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Institution: | (1) CRMD, CNRS University, 1B rue de la Férollerie, 45071 Orléans Cedex 02, France;(2) Poznan University of Technology, ul. Piotrowo 3, 60-965 Poznan, Poland |
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Abstract: | The performance of supercapacitors based on different materials with pseudocapacitive properties such as several conducting
polymers (ECPs), amorphous manganese dioxide (a-MnO2), and activated carbon is reported. Composite electrodes of high resiliency and good electronic conductivity were obtained
by mixing the active materials with carbon nanotubes. The various limitations of all the above-mentioned materials, when used
as negative and positive electrodes in traditional symmetric systems, are shown. It is demonstrated that a successful application
of ECPs and a-MnO2 in supercapacitor technologies is possible only in an asymmetric configuration, i.e. with electrodes of different nature
for positive and negative polarizations. Several types of asymmetric capacitors were developed by combining ECPs, a-MnO2, and activated carbon and characterized in aqueous electrolyte by galvanostatic charge–discharge, cyclic voltammetry, and
impedance spectroscopy. The best device considering the specific energy and power is the asymmetric supercapacitor using a-MnO2 and poly(3,4-ethylenedioxythiophene) (PEDOT) for the positive and negative electrodes, respectively. It has an operating
voltage of 1.8 V, which is attributed to different operating potentials of both electrodes, and good electrochemical stability
in neutral aqueous electrolyte. According to the voltage value, the energy density of the asymmetric capacitor at a current
density of 250 mA/g is found to be 13.5 W h/kg, which is about ten times more than for a symmetric capacitor based on PEDOT
in an aqueous medium. The asymmetric capacitor provides two times higher power than a symmetric capacitor based on activated
carbon in organic electrolyte, and is thus extremely promising for the development of environmentally friendly systems.
PACS 82.45.Wx; 82.45.Yz; 82.47.Uv; 82.35.Cd |
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