Synthesis and characterization of pyrrolidin-2-one fused N-confused calix[4]phyrins |
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Authors: | Li Xiaofang Chmielewski Piotr J Xiang Junfeng Xu Jialiang Li Yuliang Liu Huibiao Zhu Daoben |
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Affiliation: | CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P.R. China. |
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Abstract: | [reaction: see text] A facile method for the synthesis of pyrrolidin-2-one fused N-confused calix[4]phyrins is provided by reactions of 5,10,15,20-tetraaryl-2-aza-21-carbaporphyrin with acyl chlorides in the presence of triethylamine. The (1)H NMR and UV-vis spectra of products indicate their loss of macrocyclic aromaticity. |
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