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Synthesis and characterization of pyrrolidin-2-one fused N-confused calix[4]phyrins
Authors:Li Xiaofang  Chmielewski Piotr J  Xiang Junfeng  Xu Jialiang  Li Yuliang  Liu Huibiao  Zhu Daoben
Affiliation:CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P.R. China.
Abstract:[reaction: see text] A facile method for the synthesis of pyrrolidin-2-one fused N-confused calix[4]phyrins is provided by reactions of 5,10,15,20-tetraaryl-2-aza-21-carbaporphyrin with acyl chlorides in the presence of triethylamine. The (1)H NMR and UV-vis spectra of products indicate their loss of macrocyclic aromaticity.
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