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Molybdatophosphoric Acid/NaNO2 as an Efficient Procedure for the Chemoselective N‐Nitrosation of Secondary Amines |
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| Authors: | Mohammad Ali Zolfigol Khodabakhsh Niknam Fariba Nazari |
| Abstract: | A combination of molybdatophosphoric acid and sodium nitrite in the presence of wet SiO2 was used as an effective nitrosating agent for the nitrosation of secondary amines under mild and heterogeneous conditions in good to excellent yields. Also, the results of a computational study are investigated in the gas phase for geometry and properties of proposed structures. |
| Keywords: | Molybdatophosphoric acid N‐nitrosation Chemoselective Secondary amines Computational study |