Homolytic Substitution at the Sulfur Atom as a Tool for Organic Synthesis |
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Authors: | David Crich |
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Abstract: | The use of intramolecular homolytic substitution at the sulfur atom by aryl and vinyl radicals, as an alternative to the use of alkyl halides, and chalcogenides as radical precursors in organic synthesis is reviewed. |
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Keywords: | Homolytic substitution Acyl radicals Sulfoxides Sulfones Esters, thiol‐derived |
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