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Study on the Reductive Acylation of Azo Compounds by SmI2/THF in One Pot |
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| Authors: | Xue Li Yong‐Min Zhang |
| Abstract: | Azobenzene compounds without big substituents were conveniently reduced by a system consisting of SmI2/THF and successively reacted smoothly with analogous aliphatic acyl chlorides or acid anhydrides to afford corresponding mono‐acyl symmetrical hydrazobenzene under mild and neutral conditions in one pot; while other azo compounds reacted under similar conditions, amides were the terminate products. |
| Keywords: | Azo compound Reduction Acylation Samarium diiodide |