| 铜(Ⅱ)与2，2′-联吡啶胺(dpa)和3-苯丙酸(HPPr)混配配合物的合成、晶体结构及表征 |
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| 作者姓名： | 冯旭文 龚钰秋 蒋银土 顾建明 |
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| 作者单位： | 杭州大学化学系,杭州,310028 |
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| 摘 要： | The new titled complex ［Cu(dpa)(PPr)2］·2H2O was prepared and characterized by elementary analyses, IR, molar conductance and differential thermal analyses. The crystal structure was determined by X-ray diffraction. The crystal belongs to triclinic, space group P1, with the crystal cell parameters: a=10.451(2) nm, b=11.126(1) nm, c=11.795(1) nm, α=90.57(1)°, β=90.34(1)°, γ=87.89(1)°, V=1370.6(4) nm3, Z=2, Dc=1.369 g/cm3, R=0.037, RW=0.038. Four carboxyl oxygen atoms from two PPr- and two nitrogen atoms from dpa coordinate with Cu(Ⅱ) respectively to form an elongated octahedron.
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| 关 键 词： | 铜(Ⅱ)配合物 晶体结构 性质表征 |
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