| 强酸性阳离子交换树脂催化合成马来酸二异戊酯 |
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| 引用本文： | 丁亮中,罗新湘,俞善信.强酸性阳离子交换树脂催化合成马来酸二异戊酯[J].合成化学,2002,10(2):156-157,160. |
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| 作者姓名： | 丁亮中 罗新湘 俞善信 |
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| 作者单位： | 益阳师范高等专科学校化学系,湖南,益阳,413049 |
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| 基金项目： | 湖南省自然科学基金资助项目 (OOJJY2 0 1 1 0 )，湖南省教育厅科研资助项目 (OOC0 1 5) |
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| 摘 要： | 以强酸性阳离子交换树脂为催化剂催化异戊醇与马来酸酐反应合成了马来酸二异戊酯。在马来酸酐50mmol，异戊醇200mmol和强酸性阳离子交换树脂4.0g，回流分水60min的条件下，马来酸二异戊酯收率达92.2%，树脂重复使用5次，其活性未发生明显的变化。
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| 关 键 词： | 马来酸二异戊酯 强酸性阳离子交换树脂 催化合成 异戊醇 马来酸酐 |
| 文章编号： | 1005-1511(2002)02-156-02 |
Synthesis of Diisopentyl Maleate Catalyzed by Strong Acid Cation Exchange Resin |
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| DING Liang zhong,LUO Xin xiang,YU Shan xin.Synthesis of Diisopentyl Maleate Catalyzed by Strong Acid Cation Exchange Resin[J].Chinese Journal of Synthetic Chemistry,2002,10(2):156-157,160. |
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| Authors: | DING Liang zhong LUO Xin xiang YU Shan xin |
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| Abstract: | The synthesis of diisopentyl maleate from isopentyl alcohol and maleic anhydride using a strong acid cation exchange resin as a catalyst has been studied. When 50mmol maleic anhydride and 200mmol isopentyl alcohol were refluxed to segregate water for 60min in the presence of 4.0g strong acid cation exchange resin, diisopentyl maleate was obtained with 92.2% yield. The resin was reused for 5 times without any obvious less of catalytic activity. |
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| Keywords: | diisopentyl maleate isopentyl alcohol maleic anhydride synthesis strong acid cation exchange resin catalysis |
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