Infrared spectrum of hydrogen in the condensed phase with high-sensitivity spectrometers: Experiments with a 0.04-cm−1 Fourier transform spectrometer in the range 1.5–12 μm |
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Authors: | TK Balasubramanian James R Gaines K Narahari Rao EK Damon RJ Nordstrom |
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Institution: | 1. Department of Physics, The Ohio State University, Columbus, Ohio 43210 USA;2. Department of Engineering, The Ohio State University, Columbus, Ohio 43210 USA |
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Abstract: | The infrared spectrum of solid and liquid hydrogen was recorded using a Fourier spectrometer. The pure rotational U transitions, U0(0) in solid para hydrogen and U0(1) in solid normal hydrogen, with the accompanying phonon branches were observed for the first time. In addition, the rotational double transitions S0(0) + S0(1) and S0(1) + S0(1) were identified. The identifications of these transitions are based on positions calculated by making use of gas phase molecular constants. In the liquid the double transitions are preserved but the single transitions U0(0) and U0(1) are entirely absent. The region of Q1←0(J) reveals structure which has not been reported before. Its interpretation is presented. |
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