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Detection of the hydrogen-bond stretching mode in the low-frequency Raman spectrum of catechol and catechol-D2
Authors:Henrik Konschin  Henrik Tylli
Affiliation:Department of Chemistry, University of Helsinki, E. Hesperiankatu 4, SF-00100 Helsinki 10 Finland
Abstract:Low-frequency Raman spectra of catechol (1,2-dihydroxybenzene) and catechol-d2 have been measured at 130 K. The stretching mode of the intermolecular hydrogen bond, νσ, has been assigned at 187 and 184 cm?1, respectively. A short discussion of this assignment and its implications with respect to the previously reported guaiacol (2-methoxyphenol) spectra is presented.
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