The torsional spectrum of chlorine nitrate |
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Authors: | KV Chance WA Traub |
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Institution: | Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, Massachusetts 02138 USA |
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Abstract: | The far-infrared torsional spectrum of ClONO2 (chlorine nitrate) was reexamined at 0.06-cm?1 apodized resolution. The torsional spectrum consists of a single, regularly spaced series of Q branches at 122.56 ? 2.422 v′ + 0.0296 v′2 cm?1. Chlorine nitrate is planar with torsional potential constants V2 = 1900 ± 100 cm?1 and V4 = 90 ± 50 cm?1. The torsional partition function is calculated at room and stratospheric temperatures. |
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