Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering |
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| Authors: | Majumder Arpi Choudhury Chirantan Roy Mitra Samiran Rosair Georgina M El Fallah M Salah Ribas Joan |
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| Institution: | Department of Chemistry, Jadavpur University, Kolkata-700 032, India. smitra_2002@yahoo.com |
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| Abstract: | Atmospheric CO2 fixation by an aqueous solution containing Cu(ClO4)2.6H2O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional mu3-CO3 bridged copper(II) complex {Cu(4-apy)2]3(mu3-CO3)2(ClO4)2.(1/2)CH3OH}n that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex exhibits long-range ordered ferromagnetic coupling. |
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