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硫化镉复合光催化剂在模拟有机污染物体系中光催化制氢研究
引用本文:敬登伟,汤文东,邢婵娟,郭烈锦. 硫化镉复合光催化剂在模拟有机污染物体系中光催化制氢研究[J]. 燃料化学学报, 2011, 39(2): 135-139
作者姓名:敬登伟  汤文东  邢婵娟  郭烈锦
作者单位:State Key Laboratory of Multiphase Flow in Power Engineering, Xian Jiaotong University, Xian 710049, China
基金项目:国家重点基础研究发展规划
摘    要:太阳能光催化分解水制氢是太阳能制氢的最佳途径之一.选择CdS为敏化剂,制备了可见光响应的CdS复合钛酸纳米管光催化剂.以所制备的光催化剂在不同模拟有机污染物中的光催化产氢活性进行研究,对有机物浓度、pH值等反应参数进行了考察,并对其产氢机理进行了分析.研究发现各类有机物中,甲酸溶液中产氢量活性最高.分别考察了10%、2...

关 键 词:有机物  光催化  氧化物半导体催化剂  氢能
收稿时间:2010-07-22

Study on photocatalytic hydrogen production in simulated organic pollutants over cadmium sulfide composite photocatalyst
JING Deng-wei,TANG Wen-dong,XING Chan-juan,GUO Lie-jin. Study on photocatalytic hydrogen production in simulated organic pollutants over cadmium sulfide composite photocatalyst[J]. Journal of Fuel Chemistry and Technology, 2011, 39(2): 135-139
Authors:JING Deng-wei  TANG Wen-dong  XING Chan-juan  GUO Lie-jin
Abstract:Solar photocatalytic water splitting is one of the best ways for solar hydrogen production. In this paper, CdS is chosen as sensitizer to construct a CdS/titanate nanotube composite semiconductor. Both the concentrations and pH conditions of photocatalytic hydrogen production in different organic agents were investigated. The hydrogen production mechanism was analyzed. It was found that formic acid showed highest activity among various organic agents. Various concentrations with 10%, 20%, 30%, 40% and 50% were investigated and the 20% of formic acid showed best activity.
Keywords:  font-size: 10.5pt,line-height: 150%"  >organism,photocatalysis,oxide semiconductor,hydrogen,
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