Direct intramolecular arylation of unactivated arenes: application to the synthesis of aporphine alkaloids |
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| Authors: | Lafrance Marc Blaquière Nicole Fagnou Keith |
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| Affiliation: | Center for Catalysis Research and Innovation, University of Ottawa, Department of Chemistry, 10 Marie Curie, Ottawa, Canada K1N 6N5. |
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| Abstract: | The direct intramolecular C-H arylation of unactivated arenes is a viable strategy for the synthesis of aporphine alkaloids. These reactions occur with 3 to 5 mol% catalyst and generate the aporphine skeleton in up to 99% yield. |
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