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A New Tetranuclear Copper(Ⅰ) Complex of Dithiolate Ligand Fused with TTF Moiety
作者姓名:Jie DAI   Guo Qing BIAN and (Department of Chemistry  Suzhou University  Suzhou 215006)Megumu MUNAKATA   Yasuhiro OHNO   Yusaku SUENAGA (Department of Chemistry  Kinki University  Higashi-Osaka 577  Japan)
作者单位:Jie DAI; Guo Qing BIAN and (Department of Chemistry,Suzhou University,Suzhou 215006)Megumu MUNAKATA; Yasuhiro OHNO; Yusaku SUENAGA (Department of Chemistry,Kinki University,Higashi-Osaka 577,Japan)
摘    要:Dithiolatemetalcomplexeshavegeneratedgreatinterestforalongtimeduetoitsuniqueelectronicandmagneticpropertieshave.Recently,anewsystemofdithiolateligands,combinedwiththeTTFmoiety,hasreceivedmuchattentionl.Underhilletal.havereportedonthestrUcturesofadianionicmercurycomplex[Nme412[Hg(C1oH1oS8)8],andlateronaplanarneutralnickelcomplex[Ni(C,,H,,S,),]"'.Strongdrr-pninteractionbetweenthecentralmetalionandtheconjugatedligands,andtherichredoxbehaviorsofthesecomplexesimplyagoodpotentialinitSapplicati…

关 键 词:copper (Ⅰ) complex   TTF derivative   crystal structure  cluster
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