Extraction of Unprotected Amino Acids by Mixed-Ligand Nickel(II) and Copper(II) Chelates |
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Authors: | Yoshinori Ihara Shinji Kurose Takashi Koyama |
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Affiliation: | (1) Department of Chemistry, Faculty of Education, Kanazawa University, Kanazawa 920-1192, Japan, JP |
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Abstract: | Summary. Six mixed-ligand Nickel(II) and Copper(II) chelates with square-planar geometry of the formula [Ni/Cu(O-O)(S-tmpn)]B(C6H5)4 were prepared, where O-O represents acetylacetonate, tropolonate, or hinokitiolate and S-tmpn is (S)-tetramethyl-1,2-propanediamine. The compounds were investigated with respect to their function as receptor for unprotected amino acids, taking advantage of their high solubilities in non-polar organic solvents. In liquid-liquid extraction experiments between a 1,2-dichloroethane phase containing the metal chelates and an aqueous phase containing amino acids (rac-phenylglycine, rac-phenylalanine, or rac-tryptophan), the nickel(II) chelates effectively extracted amino acids from the aqueous phases under neutral conditions, forming octahedral ternary chelates. Received February 19, 2001. Accepted April 2, 2001 |
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Keywords: | . Mixed-ligand chelate Extraction of amino acids Solvatochromism. |
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