Isolating fluorinated carbocations |
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Authors: | Douvris Christos Stoyanov Evgenii S Tham Fook S Reed Christopher A |
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Institution: | Center for S and P Block Chemistry, Department of Chemistry, University of California, Riverside, California 92521, USA. |
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Abstract: | Using carboranes as counterions, fluorinated benzyl-type carbocations such as (p-FC(6)H(4))(2)CF(+), (p-FC(6)H(4))(CH(3))CF(+) and fluorinated trityl ions are readily isolated for X-ray and IR structural characterization. |
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