Synthesis,molecular, crystal and electronic structure of [RuCl2(PPh3)2(3,5-Me2HPz)2] |
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| Authors: | J. G. Małecki R. Kruszynski |
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| Affiliation: | (1) Department of Inorganic and Radiation Chemistry, Institute of Chemistry, University of Silesia, 9th Szkolna St., Katowice, 40-006, Poland;(2) X-Ray Crystallography and Crystal Chemistry Group, Institute of General and Ecological Chemistry, Technical University of Łódź, 116 Żeromski St., Lodz, 90-924, Poland |
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| Abstract: | The reaction of [RuCl2(PPh3)3] complex with dimethylpyrazole has been examined. A new ruthenium complex—[RuCl2(PPh3)2(3,5-Me2HPz)2] has been obtained and characterized by IR, 1H NMR and UV-VIS measurements. Crystal and molecular structure of the complex has been determined. The electronic structure of the complex has been calculated by TDDFT method. |
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| Keywords: | Ruthenium 3,5-Dimethylpyrazole X-ray structure Tertiary phosphine complexes TDDFT |
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