Reactions of Pd β-Diketonate Complexes with Triethylaluminium |
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| Authors: | L B Belykh T V Goremyka A V Rokhin Yu Yu Titova V A Umanets F K Schmidt |
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| Institution: | (1) Irkutsk State University, Irkutsk, Russia |
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| Abstract: | Reactions of Pd(Acac)2 and Pd(Acac)2PPh3 complexes with triethylaluminium in an inert atmosphere are studied by the NMR and IR, electronic microscopy, and X-ray powder diffraction methods. The final products of conversion of the initial Pd(II) complexes are the Pd(0) nanoparticles with the predominant diameter 2–4 nm. The main factors determining the size of Pd(0) particles and the nature of the ligand shell are considered. |
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