Note sur la préparation et la scission de l'acide (diméthyl-3, 3-butyl)-phosphorique |
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Authors: | Emile Cherbuliez O. Espejo S. Jaccard J. Rabinowitz |
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Abstract: | 3,3-Dimethylbutanol treated with polyphosphoric acid or with an equimolecular amount of POCl3 gives rise to 3,3-dimethylbutyl phosphoric acid, isolated as baryum salt (yield 20 to 30%) or as sodium salt (yield 15%). Stable in NaOH 1N at 100°C, this monoester is split at pH 4.5 and in HCl 1N much slower than choline phosphate. |
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