Reaction of N-substituted 2,5-dialkyl-1,4-benzoquinone imines with arenesulfinic acids |
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Authors: | A. P. Avdeenko S. A. Konovalova D. A. Roman’kov O. N. Ludchenko I. L. Marchenko |
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Affiliation: | (1) Donbass State Machine-Building Academy, ul. Shkadinova 72, Kramatorsk, 84313, Ukraine |
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Abstract: | Reactions of N-aroyl-, N-arylsulfonyl-, and N-(N-arylsulfonylbenzimidoyl)-2,5-dialkyl-1,4-benzoquinone imines with sodium arenesulfinates in acetic acid gave the corresponding 1,4-, 6,1-, and 1,6-addition products. Variation of the size and donor power of substituents in positions 2 and 5 of the quinoid ring almost does not affect the ratio of the addition products, which is determined mainly by the nature of substituent on the nitrogen atom. |
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